Publications

Last updated:

42.

“Efficient Removal of Short‐Chain Perfluoroalkyl Substances by Cavity‐Directed Aggregation in a Molecular Cage Host”
C. V. I. Andersson, S. G. T. Mudiyanselage, M. D. Peeks, A. A. Kroeger, J. I. Virtue, M. Mann, J. M. Chalker, M. L. Coote, M. R. Johnston*, & W. M. Bloch*.
Angew. Chem. Int. Ed. 2026, 65, 12, e26027.
DOI: 10.1002/anie.202526027

41.

“Spontaneous trisulfide metathesis in polar aprotic solvents”
H. D. Patel, A. D. Tikoalu, J. N. Smith, Z. Pei, S. J. Tonkin, R. Shapter, P. Yan, S. Tsoukatos, W. M. Bloch, M. R. Johnston, J. R. Harmer, C. T. Gibson, M. V. Perkins, T. Hasell, M. L. Coote*, Z. Jia*, & J. M. Chalker*.
Nat. Chem. 2026, 1–10.
DOI: 10.1038/s41557-026-02091-z

40.

“Thermal imaging using sulfur polymer optics”
S. J. Tonkin, H. D. Patel, J. M. M. Pople, L. N. Pham, D. J. Lewis, B. A. Aljubran, J. R. Gascooke, C. T. Gibson, T. Hewagama, D. E. Jennings, F. T. Ferguson, M. R. Johnston, W. M. Bloch, A. C. Bissember, Z. Jia, M. L. Coote, & J. M. Chalker*.
Nat. Commun. 2026, 17, 1, 1561.
DOI: 10.1038/s41467-026-68889-0

39.

“Steering the Shape‐shifting of Bullvalene‐PdII Complexes Through Steric and Geometric Strain”
A. P. Birvé, W. M. Bloch*, & T. Fallon*.
Angew. Chem. Int. Ed. 2026, e23441.
DOI: 10.1002/anie.202523441

38.

“Making and Unmaking Poly(trisulfides) with Light: Precise Regulation of Radical Concentrations via Pulsed LED Irradiation”
T. P. Nicholls*, J. M. M. Pople, M. R. Harvey, H. D. Patel, A. K. Mann, S. J. Tonkin, J. D. Randall, A. Wickramasingha, J. Y. J. Wang, J. C. Robertson, L. N. Pham, J. R. Gascooke, L. C. Henderson, C. T. Gibson, W. M. Bloch, S. J. Fraser-Miller, D. R. Jones, Z. Jia, M. L. Coote, A. C. Bissember, & J. M. Chalker.
J. Am. Chem. Soc. 2025 147, 50, 46243–46258..
DOI: 10.1021/jacs.5c15051

37.

“Europium metal–organic framework polymer composites with enhanced luminescence and selective ferric ion sensing”
L. Rozenberga, W. M. Bloch, T. A. Gillam, D. G. Lancaster, W. Skinner, M. Krasowska, A. Blencowe, & D. A. Beattie
ACS Appl. Polym. Mater. 2024, 6, 6, 3544–3553.
DOI: 10.1021/acsapm.4c00111

36.

“Halide-triggered assembly and selective bisulfate recognition in a quadruply interlocked coordination cage”
J. I. Virtue, S. Tsoukatos, M. R. Johnston, & W. M. Bloch*.
Chem. Sci. 2024, 15, 45, 19119–19125.
DOI: 10.1039/D4SC04913F

35.

“Topological control in paddlewheel metal–organic cages via ligand length variation”
S. Tsoukatos, A. Maibam, R. Babarao, & W. M. Bloch*.
Chem. Commun. 2024, 60, 90, 13183–13186.

ChemComm 60th Anniversary Collection
DOI: 10.1039/D4CC03769C

34.

“Topological analysis and control of post-synthetic metalation sites in Zr-based metal–organic frameworks”
P. Gimeno-Fonquernie, J. Albalad, J. R. Price, W. M. Bloch, J. D. Evans, C. J. Doonan, & C. J. Sumb.
J. Mater. Chem. C 2024, 12, 7, 2359–2369.
DOI: 10.1039/D3TC03606E

33.

“Electrochemical synthesis of poly(trisulfides)”
J. M. M. Pople, T. P. Nicholls, L. N. Pham, W. M. Bloch, L. S. Lisboa, M. V. Perkins, C. T. Gibson, M. L. Coote, Z. Jia, & J. M. Chalker..
J. Am. Chem. Soc. 2023, 145, 21, 11798–11810
DOI: 10.1021/jacs.3c03239

32.

Maximized axial helicity in a Pd₂L₄ cage: inverse guest size-dependent compression and mesocate isomerism
W. M. Bloch*, S. Horiuchi, J. J. Holstein, C. Drechsler, A. Wuttke, W. Hiller, R. A. Mata, & G. H. Clever*.
Chem. Sci. 2023, 14, 6, 1524–1531.

Most popular 2023 polymer and supramolecular chemistry articles
DOI: 10.1071/CH19215

31.

“Assembly of a heterometallic Cu(II)–Pd(II) cage by post-assembly metal insertion”
M. T. Yong, O. M. Linder-Patton, & W. M. Bloch*.
Inorg. Chem. 2022, 61, 32, 12863–12869.
DOI: 10.1021/acs.inorgchem.2c02046

30.

“A europium metal–organic framework for dual Fe³⁺ ion and pH sensing”
L. Rozenberga, W. Skinner, D. G. Lancaster, W. M. Bloch*, A. Blencowe, M. Krasowska, & D. A. Beattie*.
Sci. Rep. 2022, 12, 1, 11982.
DOI: 10.1002/asia.70331

29.

“Guest-Dependent Isomer Convergence of a Permanently Fluxional Coordination Cage”
A. P. Birvé, H. D. Patel, J. R. Price, W. M. Bloch*, & T. Fallon*.
Angew. Chem. Int. Ed. 2022, 134, 9, e202115468.

VIP
DOI: 10.1002/anie.202115468

28.

“Polymer networks of imine-crosslinked metal–organic cages: tuneable viscoelasticity and iodine adsorption”
M. L. Schneider, J. A. Campbell, A. D. Slattery, & W. M. Bloch*.
Chem. Commun. 2022, 58, 12122–12125.

2022 Emerging Investigators
DOI: 10.1039/D2CC04969D

27.

“Linking metal–organic cages pairwise as a design approach for assembling multivariate crystalline materials”
A. W. Markwell-Heys, M. Roemelt, A. D. Slattery, O. M. Linder-Patton, & W. M. Bloch*.
Chem. Sci. 2022, 13, 1, 68–73.

2021 Chemical Science HOT Article Collection
DOI: 10.1039/D1SC05663H

26.

“Assembly and covalent cross-linking of an amine-functionalised metal-organic cage”
M. L. Schneider, A. W. Markwell-Heys, O. M. Linder-Patton, & W. M. Bloch*.
Front. Chem. 2021, 9, 696081.

Frontiers in Chemistry – Rising Stars: Oceania
DOI: 10.1002/anie.202500264

25.

“Self-sorting of porous Cu₄L₂L′₂ metal–organic cages composed of isomerisable ligands”
A. W. Markwell-Heys, M. L. Schneider, J. M. L. Madridejos, G. F. Mehta, & W. M. Bloch*.
Chem. Commun. 2021, 57, 23, 2915–2918.
DOI: 10.1039/D0CC08076D

24.

“A covalent deprotection strategy for assembling supramolecular coordination polymers from metal–organic cages”
M. L. Schneider, O. M. Linder-Patton, & W. M. Bloch*.
Chem. Commun. 2020, 56, 85, 12969–12972.
DOI: 10.1039/D0CC05349J

23.

“On/off porosity switching and post-assembly modifications of Cu₄L₄ metal–organic polyhedra”
W. M. Bloch*, R. Babarao, & M. L. Schneider.
Chem. Sci. 2020, 11, 14, 3664–3671.

Most popular 2019-2020 inorganic, main group and crystal engineering chemistry articles
DOI: 10.1039/D0SC00070A

22.

Tuning Packing, Structural Flexibility, and Porosity in 2D Metal–Organic Frameworks by Metal Node Choice
W. M. Bloch*, C. J. Doonan, & C. J. Sumby*.
Aust. J. Chem. 2019, 72, 10, 797–804.
DOI: 10.1071/CH19215

21.

“Isomer Interconversion Studied through Single-Crystal to Single-Crystal Transformations in a Metal–Organic Framework Matrix”
M. T. Huxley, R. J. Young, W. M. Bloch, N. R. Champness*, C. J. Sumby*, & C. J. Doonan*.
Organometallics 2019, 38, 18, 3412–34181.
DOI: 10.1021/acs.organomet.9b00401

20.

“Donor-Site-Directed Rational Assembly of Heteroleptic cis-[Pd2L2L′2] Coordination Cages from Picolyl Ligands”
R. Zhu, W. M. Bloch, J. J. Holstein, S. Mandal, L. V. Schäfer, G. H. Clever*.
Chem. Eur. J. 2018, 24, 12976–12982.
DOI: 10.1002/chem.201802188

19.

“Hierarchical Assembly of an Interlocked M8L16 Container”
W. M. Bloch*, J. J. Holstein, B. Dittrich, W. Hiller, G. H. Clever*.
Angew. Chem. Int. Ed. 2018, 57, 5534–5538.
DOI: 10.1002/anie.201800490

18.

“Morphological Control of Heteroleptic cis- and trans-Pd2L2L′2 Cages”
W. M. Bloch, J. J. Holstein, W. Hiller, G. H. Clever*.
Angew. Chem. Int. Ed. 2017, 56, 8285–8289.
DOI: 10.1002/anie.201702573

17.

“Engineering isoreticular 2D metal–organic frameworks with inherent structural flexibility”
A. Burgun, W. M. Bloch, C. J. Doonan*, C. J. Sumby*.
Aust. J. Chem. 2017, 70, 566–575.
DOI: 10.1071/CH16663

16.

“X-ray crystallographic insights into post-synthetic metalation products in a metal–organic framework”
M. T. Huxley, C. J. Coghlan, W. M. Bloch, A. Burgun, C. J. Doonan*, C. J. Sumby*.
Phil. Trans. R. Soc. A 2017, 375, 2084.
DOI: 10.1098/rsta.2016.0028

15.

“Integrative self-sorting of coordination cages based on ‘naked’ metal ions”
W. M. Bloch, G. H. Clever*.
Chem. Commun. 2017, 53, 8506–8516.
DOI: 10.1039/C7CC03379F

14.

“Geometric Complementarity in Assembly and Guest Recognition of a Bent Heteroleptic cis-[Pd2LA2LB2] Coordination Cage”
W. M. Bloch, Y. Abe, J. J. Holstein, C. M. Wandtke, B. Dittrich, G. H. Clever*.
J. Am. Chem. Soc. 2016, 138, 13750–13755.
DOI: 10.1021/jacs.6b08694

13.

“Particle size effects in the kinetic trapping of a structurally-locked form of a flexible MOF”
O. M. Linder-Patton, W. M. Bloch, C. J. Coghlan, K. Sumida, S. Kitagawa, S. Furukawa, C. J. Doonan, C. J. Sumby*.
CrystEngComm 2016, 18, 4172–4179.
DOI: 10.1039/C6CE00082G

12.

“Silver(I) coordination polymers of the ‘hinged’ pyrazine containing ligand di-2-pyrazinylmethane”
W. M. Bloch, C. J. Sumby*.
Supramol. Chem. 2015, 27, 807–819.
DOI: 10.1080/10610278.2015.1078465

11.

“X-ray crystallography in open-framework materials”
W. M. Bloch, N. R. Champness*, C. J. Doonan*.
Angew. Chem. Int. Ed. 2015, 54, 12860–12867.
DOI: 10.1002/anie.201501545

10.

“Probing solid-state breathing and structural transformations in a series of silver(I) porous coordination polymers”
W. M. Bloch, C. J. Sumby*.
Eur. J. Inorg. Chem., 2015, 3723–3729.
DOI: 10.1002/ejic.201500647

9.

“Probing post-synthetic metallation in metal–organic frameworks: insights from X-ray crystallography”
W. M. Bloch, A. Burgun, C. J. Doonan*, C. J. Sumby*.
Chem. Commun. 2015, 51, 5486–5489.
DOI: 10.1039/C4CC09639H

8.

“Capturing snapshots of post-synthetic metallation chemistry in metal–organic framework”
W. M. Bloch, A. Burgun, C. J. Coghlan, R. Lee, M. L. Coote, C. J. Doonan*, C. J. Sumby*.
Nat. Chem. 2014, 6, 906–912.
DOI: 10.1038/nchem.2045

7.

“Does functionalisation enhance CO₂ uptake in interpenetrated MOFs? An examination of the IRMOF-9 series”
R. Babarao*, C. J. Coghlan, D. Rankine, W. M. Bloch, G. K. Gransbury, H. Sato, S. Kitagawa, C. J. Sumby, M. R. Hill*, C. J. Doonan*.
Chem. Commun. 2014, 50, 3238–3241.
DOI: 10.1039/C4CC00700J

6.

“Post-synthetic structural processing in a metal–organic framework material as a mechanism for exceptional CO₂/N₂ selectivity.”
W. M. Bloch, R. Babarao, M. R. Hill, C. J. Doonan*, C. J. Sumby*.
J. Am. Chem. Soc. 2013, 135, 10441–10448.
DOI: 10.1021/ja4032049

5.

“Using hinged ligands to target structurally flexible copper(II) MOFs”
W. M. Bloch, C. J. Doonan*, C. J. Sumby*.
CrystEngComm 2013, 15, 9663–9671.
DOI: 10.1039/C3CE41244J

4.

“Biomimetic total synthesis of (±)-garcibracteatone”
H. P. Pepper, H. C. Lam, W. M. Bloch, J. H. George*.
Org. Lett. 2012, 14, 5162–5164.
DOI: 10.1021/ol302524q

3.

“Total Synthesis of (+)-Aureol”
K. K. W. Kuan, H. P. Pepper, W. M. Bloch, J. H. George*.
Org. Lett. 2012, 14, 4710–4713.
DOI: 10.1021/ol301715u

2.

“Guest-induced crystal-to-crystal expansion and contraction of a 3-D porous coordination polymer”
W. M. Bloch, C. J. Sumby*.
Chem. Commun. 2012, 48, 2534–2536.
DOI: 10.1039/C2CC17440E

1.

“Fused pyrazino[2,3-b]indolizine and indolizino[2,3-b]quinoxaline derivatives; synthesis, structures, and properties”
W. M. Bloch, S. M. Derwent-Smith, F. Issa, J. C. Morris, L. M. Rendina, C. J. Sumby*.
Tetrahedron 2011, 67, 9368–9375.
DOI: 10.1016/j.tet.2011.09.133